by Leonard David,’s Space Insider Columnist

NASA's Mars rover Curiosity just might be the latest in a long line of Mars-exploring robots to discover the building blocks for primitive life on the Red Planet.

The Curiosity rover may have gathered evidence for the presence of perchlorates in Rocknest — a sand patch inside the rover's Gale Crater landing site on the Red Planet, scientists say. If so, it shores up the case that the material may well be globally distributed on Mars.

Not only can perchlorates, which are a class of salts, serve as an energy source for potential Martian microorganisms, they are also a sensitive marker of past climate and can lead to the formation of liquid brines under current conditions on the planet.

The possibility that perchlorates are widespread on Mars was detailed in a March 19 presentation at the 44th annual Lunar and Planetary Science Conference in The Woodlands, Texas.

Curiosity's possible detection

The possible detection of perchlorates at Curiosity’s Gale crater site was spotlighted by Doug Archer, a scientist with the Astromaterials Research and Exploration Science Directorate of NASA's Johnson Space Center in Houston. He is focused on the habitability of various Martian environments over time. [The Search for Life on Mars (A Photo Timeline)]

Archer pointed to the rover’s Sample Analysis at Mars (SAM) instrument suite that recently ran four samples from Rocknest. That area was selected as the source of the first samples analyzed because it is representative of both windblown material in the Gale Crater and the planet's globally distributed dust, he said.

"When we heated this up, we saw a large oxygen release at the same time we saw the release of these chlorinated hydrocarbons," Archer said, thus making a strong case for the presence of perchlorate salts in Rocknest's soil.

Phoenix finding

Perchlorates were first identified on Mars in the polar region by the Wet Chemistry Laboratory on NASA’s Phoenix lander in 2008.

This detection of perchlorates was corroborated by an oxygen release observed by the polar lander’s Thermal and Evolved Gas Analyzer instrument during analysis of a soil sample similar to the oxygen released from Rocknest samples, Archer said.

Archer reported that the prospect of perchlorates in Rocknest material adds weight to the argument that both Viking landers in 1976 measured signatures of perchlorates, in the form of chlorinated hydrocarbons.

Similarly, Archer noted that other Mars robots — Sojourner, Spirit and Opportunity — also detected elemental chlorine. Moreover, orbital measurements by the Gamma Ray Spectrometer on the Mars Odyssey spacecraft show that chlorine is globally distributed at similar levels.

Implications for habitability

"In all of these missions, we haven't always used the same technique … but we have always had the ability to measure chlorine in one way or another," Archer said. "If you look at these measurements at all of the landing sites … chlorine is relatively consistent in Martian soils," he said.

"I'm not saying that all of this chlorine everywhere on Mars is in the form of perchlorates … there are likely other chlorate salts as well," Archer said. "I believe that at least some of the chlorine at all of these locations is present as perchlorate."

Archer said that the implications of globally distributed perchlorates are very important for climate, habitability and present-day aqueous processes.

Specifically, perchlorate has important implications for Mars habitability.

"We know of microbes on the Earth that actually use perchlorate as an energy source," Archer told

But there’s a flip side to perchlorates and Martian microbes.

"Perchlorate makes organic detection very difficult because it releases a lot of oxygen," Archer said. "So that's something that life detection and organic detection missions really have to worry about."


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